Well, first up anything in CSS is legal Sass. It's 100% compatible like that, and is designed to be a superset rather than a sideways move.
The main things to care about:
* Sass by default ships as a bunch of files and you run a tool to combine them together and minify them for performance.
* Sass is all about the variables - so you define a colour once and reuse it everywhere by referencing it with a name. Modern CSS now has this too, but Sass had it *years* before.
* Sass has features about reusing things, e.g. you can do what Bootstrap does under the hood (since Bootstrap uses Sass internally), whereby define a style in CSS normally and just add an @include to mark that section as 'only include this in the md size and up' without having to remember what the size points are etc. and do all kinds of macro stuff to roll your own functions to avoid writing lots of CSS by hand.
* Tools exist to sit on top of your Sass and process it out to remove styles that you're not actually using, but that requires the tools having access to the templates etc. to review what ids and classes they're actually using.
* Tools also exist to take a collection of SVG images, build an image font and also spit out the required Sass to include for the rest of your project to use them as an icon font - just the way Font Awesome does it.